Gerken, Michael
Faculty
- Phone
- (403) 329-2173
- michael.gerken@uleth.ca
Lab
- Phone
- (403) 394-3903
Current Research
| Title |
Location |
Principal Investigator | Co-Researchers | Grant Agency |
Grant Amount |
Grant Time Period |
|---|---|---|---|---|---|---|
| Synthesis and Characterization of Transition-Metal Sulfide Fluorides, and Main-Group Fluorides and Oxide Fluorides | Lethbridge, AB | Michael Gerken, University of Lethbridge | ||||
| Synthesis and Characterization of Transition-Metal Sulfide Fluorides, and Main-Group Fluorides and Oxide Fluorides | Lethbridge, AB | Michael Gerken, University of Lethbridge | Natural Sciences and Engineering Research Council (NSERC) | $35,000 per year | 2008-12 | |
| Novel Transition Metal Sulfide Fluorides and Pentafluoro-sulfanyl Fluorides | Lethbridge, AB | Michael Gerken, University of Lethbridge | ||||
| Novel Transition Metal Sulfide Fluorides and Pentafluoro-sulfanyl Fluorides | Lethbridge, AB | Michael Gerken, University of Lethbridge | Natural Sciences and Engineering Research Council (NSERC) | $40,000/year | 2005-07 |
Publications
J. T. Goettel, N. Kostiuk, M. Gerken* "The Solid-State Structure of SF4: The Final Piece of the Puzzle" Angewandte Chemie, 2013, 125, 8195-8198; Angewandte Chemie International Edition, 2013, 52, 8037-8040. HIGHLIGHTED in Nachrichten aus der Chemie, 2013, 61, 999 and covered in TRENDS IN INORGANIC CHEMISTRY 2013 in Nachrichten aus der Chemie, 2014, 62, 233.
J. T. Goettel, P. Chaudhary, P.Hazendonk, H. P. A. Mercier, M. Gerken* "SF4•N(C2H5)3: The First Conclusively tCharacterized SF4 Adduct with an Organic Base" Chemical Communications, 2012, 48, 9120-9122.t
J. Nieboer, R. Haiges, W. Hillary, X. Yu, T. Richardet, H. P. Mercier, M. Gerken* "Fluoride-Ion Acceptor Properties of WSF4: Synthesis, Characterization, and Computational Study of the WSF5- and W2S2F9- Anions, and 19F NMR Spectroscopic Characterization of the W2OSF9- Anion" Inorganic Chemistry. 2012, 51, 6350-6359.
J. P. Mack, J. A. Boatz, M. Gerken "Synthesis, NMR and vibrational spectroscopic characterization, and computational study of the cis-IO2F32-anion" Inorganic Chemistry 2008, 47, 3243-3247.
M. Gerken, P. Hazendonk A. Iuga, J. Nieboer, M. Tramsek, E. Goreshnik, B. Zemva, S. Zheng, J. Autschbach "Solid-state NMR spectroscopic study of coordination compounds of XeF2 with metal cations and the crystal structure of [Ba(XeF2)5][AsF6]2" Inorganic Chemistry 2007, 46, 6069-6077.
J. T. Goettel, P. Chaudhary, P.Hazendonk, H. P. A. Mercier, M. Gerken* "SF4•N(C2H5)3: The First Conclusively tCharacterized SF4 Adduct with an Organic Base" Chemical Communications, 2012, 48, 9120-9122.t
J. Nieboer, R. Haiges, W. Hillary, X. Yu, T. Richardet, H. P. Mercier, M. Gerken* "Fluoride-Ion Acceptor Properties of WSF4: Synthesis, Characterization, and Computational Study of the WSF5- and W2S2F9- Anions, and 19F NMR Spectroscopic Characterization of the W2OSF9- Anion" Inorganic Chemistry. 2012, 51, 6350-6359.
J. P. Mack, J. A. Boatz, M. Gerken "Synthesis, NMR and vibrational spectroscopic characterization, and computational study of the cis-IO2F32-anion" Inorganic Chemistry 2008, 47, 3243-3247.
M. Gerken, P. Hazendonk A. Iuga, J. Nieboer, M. Tramsek, E. Goreshnik, B. Zemva, S. Zheng, J. Autschbach "Solid-state NMR spectroscopic study of coordination compounds of XeF2 with metal cations and the crystal structure of [Ba(XeF2)5][AsF6]2" Inorganic Chemistry 2007, 46, 6069-6077.
Degrees
Diplom der Chemie (equivalent to M.Sc.), Gerhard Mercator Universität Duisburg, Germany; Ph.D. (Inorganic Chemistry), McMaster University, Hamilton
Research Areas
Transition-metal sulfide fluoride chemistry
Main-group oxide fluoride chemistry
Solid-state NMR spectroscopy of inorganic fluorides
Expertise
X-ray crystallography
Vibrational spectroscopy
Solution and solid-state NMR spectroscopy
Inorganic fluorine chemistry
Languages
German